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Abstract The ionospheric O⁺number density can be measured remotely during the day by observing its optically thick 83.4 nm radiance. Some ambiguity is present in the process of retrieving the density due to uncertainties in the initial excitation rate. This can be removed by observing a companion optically thin emission at 61.7 nm originating from the O⁺(3s²P) state, providing that the ratio of the initial excitation rates is known. Analyses of ICON EUV data using an 83.4/61.7 emission ratio of order 10 result in O⁺densities lower by ∼2 than other measurements. Key to relating the two emissions is accurate knowledge of the partial photoionization cross sections and the spectroscopy of O⁺—the topic of this paper. Up to now, no independent evaluation of the ratio of the 83.4/61.6 emission ratio exists. The recent availability of state‐of‐the‐art calculations of O partial photoionization cross sections into a variety of O⁺states presents an opportunity to evaluate the O⁺(2p⁴⁴P)/O⁺(3s²P) ionization rate ratio. We calculate excitation of these parent states of the emissions including both direct and cascade excitation from higher lying O⁺energy states. The resulting theoretical prediction gives ratios that range from 13.5 to 12 from solar minimum to maximum, larger than the value of 10 used by the ICON 83.4 and 61.7 nm algorithm. The higher theoretical values for the ratio reconcile the ∼2 discrepancy between simultaneous ICON and other electron density measurements. 

Abstract Most ionospheric models cannot sufficiently reproduce the observed electron density profiles in the E‐region ionosphere, since they usually underestimate electron densities and do not match the profile shape. Mitigation of these issues is often addressed by increasing the solar soft X‐ray flux which is ineffective for resolving data‐model discrepancies. We show that low‐resolution cross sections and solar spectral irradiances fail to preserve structure within the data, which considerably impacts radiative processes in the E‐region, and are largely responsible for the discrepancies between observations and simulations. To resolve data‐model inconsistencies, we utilize new high‐resolution (0.001 nm) atomic oxygen (O) and molecular nitrogen (N₂) cross sections and solar spectral irradiances, which contain autoionization and narrow rotational lines that allow solar photons to reach lower altitudes and increase the photoelectron flux. This work improves upon Meier et al. (2007,https://doi.org/10.1029/2006gl028484) by additionally incorporating high‐resolution N₂photoionization and photoabsorption cross sections in model calculations. Model results with the new inputs show increased O⁺production rates of over 500%, larger than those of Meier et al. (2007,https://doi.org/10.1029/2006gl028484) and total ion production rates of over 125%, while production rates decrease by ∼15% in the E‐region in comparison to the results obtained using the cross section compilation from Conway (1988,https://apps.dtic.mil/sti/pdfs/ADA193866.pdf). Low‐resolution molecular oxygen (O₂) cross sections from the Conway compilation are utilized for all input cases and indicate that is a dominant contributor to the total ion production rate in the E‐region. Specifically, the photoionization contributed from longer wavelengths is a main contributor at ∼120 km.